Know how to balance a nuclear reaction.
Know the definitions and differences in the various types of nuclear decay/radiation types: fusion, fission, alpha decay, beta decay, positron emission, gamma rays/emission.
Know the definition of binding energy and how that relates to \(E = mc^2\).
\(a {\rm A} + b {\rm B} \rightarrow c {\rm C} + d {\rm D}\)
\({\rm reaction \; rate} =\) \(-{\Delta[{\rm A}]\over a\Delta t} = -{\Delta[{\rm B}]\over b\Delta t} = {\Delta[{\rm C}]\over c\Delta t} = {\Delta[{\rm D}]\over d\Delta t}\)
\({\rm rate} = k[{\rm A}]^x[{\rm B}]^y\cdots\)
\([{\rm A}]_0 - [{\rm A}] = kt \hskip24pt t_{1/2}={[{\rm A}]_0\over 2k}\)
\(\ln\left({[{\rm A}]_0 \over [{\rm A}]}\right) = kt \hskip24pt t_{1/2}={\ln2\over k}\)
\({1\over[{\rm A}]} - {1\over[{\rm A}]_0} = k t\hskip24pt t_{1/2}={1\over k[{\rm A}]_0}\)
\(k = A\,e^{-E_{\rm a}/RT}\)
\(\ln k = {-E_{\rm a}\over R}\left({1\over T}\right) + \ln A\)
\(\ln\left({k_2\over k_1}\right) = {E_{\rm a}\over R}\left({1\over T_1} - {1\over T_2}\right)\)
A Lewis base donates an electron pair (the ligand). A Lewis acid accepts an electron pair (the metal atom or cation). This is a dative bond in general although with metals and ligands the name coordinate covalent bond is more common.
monodentate charged: the halides, hydroxide, cyanide
monodentate neutral: ammonia, water, pyridine (py), carbon monoxide
bidentate charged: oxalate (ox)
bidentate neutral: ethylenediamine (en), bipyridine (bpy), phenanthroline (phen)
PLUS - if given in a formula, you should be able to recognize other ligands and their denticities.
Remember that the ligands provide a core set of electrons. For example, in a octahedral complex, the ligands provide 12 electrons. The metals then add to the ligand number via their d-orbital electrons and possibly their s-orbital electrons depending on the charge.
Periodic Table
Conversion factors
(like masses of protons, neutrons, etc...)
Students will be able to...
Students will be able to...
Students will be able to...